Not all holders of joe are made of porcelain or ceramic. Not all that aren't made of porcelain are paper coffee cups, either. People's fascination with caffeine has driven them to put java in all manner of things. Some folks even swear that joe from glass coffee cups tastes different than from a porcelain or ceramic cup, but that's obviously subjective. There are other reasons that one might choose glass cups over more traditional methods of serving java, though.
Aesthetics
Some folks like to see what they're drinking, and most cups don't allow for that. If you can't see it, how can you be sure your cafe mocha contains the correct portion of cream, and that cappuccino the right amount of milk foam? When it comes to their caffeine, not everyone "gets it", so shops might make use of glass cups to let their customers know that they're getting what they're paying for.
Durability
Glass is generally associated with being breakable but, in reality, that's not necessarily so. Like other materials, it really depends on the craftsmanship and thickness. It's also worth mentioning that it's not nearly as easy to crack or chip a glass coffee cup as it is to chip ceramic. With most modern floors having some sort of padding underneath them, the odds of dropping a glass cup and having it break are pretty slim, and certainly no worse than any other material, except plastic or metal.
Keeping Things Warm
Neither porcelain nor ceramic is particularly good at keeping things warm. They don't transfer heat particularly well, though, which is why they're typically used to serve coffee. The whole point isn't to keep the heat in so much as to give you a handle that's cool enough for human hands. Glass typically transfers heat a bit better, but glass cups are generally made to be at least as heat resistant as more traditional ones. Of course, nothing beats an aluminum or plastic insulated mug, and even disposable coffee cups with lids will keep the liquid warm longer.
They Only Look Expensive
Most people automatically assume that glass cups are expensive because they look very elegant, almost crystalline. Cups made of glass generally don't cost any more than any other decently made cup, however. There's even glass espresso coffee cups available, complete with matching glass saucers. Due to limited demand, you might not be able to find glass coffee cups locally, but you can always find them online.
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